In the L-alaninate complex, two cadmium resonances are observed which are rationalized as being due to the presence of diastereoisomers within the powders sample

Inorganic Chemistry

Solid-state 113 Cd NMR spectra have been recorded for bis(glycinato)cadmium(II) hydrate, bis(L-alaninato)cadmium(II) trihydrate, and a 1:2 comples of cadmium and L-cysteine; the principal components of the 113 Cd shielding tensor have been determined. The spectra show useful additional fine structure due to dipolar coupling (both direct and indirect) between 113 Cd and 14 N, which allows the number of nitrogens bonded to the cadmium center to be determined directly. In the L-alaninate complex, two cadmium resonances are observed which are rationalized as being due to the presence of diastereoisomers within the powders sample

In the L-alaninate complex, two cadmium resonances are observed which are rationalized as being due to the presence of diastereoisomers within the powders sample

Solid-state cadmium-113 NMR studies on cadmium complexes with glycine, L-alanine, and L-cysteine