Paper
Ammonium-directed dihydroxylation: metal-free synthesis of the diastereoisomers of 3-aminocyclohexane-1,2-diol.
Published Sep 17, 2008 · Caroline Aciro, S. Davies, P. M. Roberts
Organic & biomolecular chemistry
Q2 SJR score
38
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0
Influential Citations
Abstract
The ammonium-directed, metal-free oxidation of 3-(N,N-dibenzylamino)cyclohex-1-ene with mCPBA in the presence of either trichloroacetic acid or tosic acid has been used as the key step to facilitate the synthesis of all the diastereoisomers of 3-aminocyclohexane-1,2-diol, in >98% de in each case.
Study Snapshot
The ammonium-directed dihydroxylation allows for the synthesis of all diastereoisomers of 3-aminocyclohexane-1,2-diol in >98% de purity, making it a promising method for synthesising organic compounds.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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