Mass spectrometric analysis of aluminoxanes is difficult due to their high reactivity, thermal instability, involatility, and propensity to form complex mixtures of oligomers. However, the controlled hydrolysis of fluorobenzene solutions of triisobutylaluminum provides surprisingly simple electrospray ionization mass spectra (ESI-MS), consisting of just two main charged species. The most abundant of these can be characterized as [Al3O3iBu4(AliBu2H)2(AliBu3)]−, using a combination of m/z value, isotope pattern, MS/MS studies, and isotopic labeling.

Controlled hydrolysis of triisobutylaluminum solutions provides simple electrospray ionization mass spectra, revealing two main charged species and enabling the characterization of [Al3O3iBu4(AliBu2H)2(AliBu3)].

Paper

Characterization of Isobutylaluminoxanes by Electrospray Ionization Mass Spectrometry

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