The chlorination of (3,3,3-trifluoropropyl)trichlorosilane

doi:10.1016/S0022-328X(00)84378-8

Paper

The chlorination of (3,3,3-trifluoropropyl)trichlorosilane

Published Aug 1, 1965 · O. W. Steward, O. Pierce

Journal of Organometallic Chemistry

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3

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Abstract

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Study Snapshot

The chlorination of (3,3,3-trifluoropropyl)trichlorosilane produces products with a 6.2 times greater susceptibility to chlorine radical attack than the -position silicon CH bonds.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

Paper

The chlorination of (3,3,3-trifluoropropyl)trichlorosilane

References

Citations

Investigation of the nature of the trifluoromethyl, trifluorosilyl, and trichlorosilyl groups in the series CF3CHXCXYSiF3 and CF3 CHXCXYSiCl3

The SiF3 group deactivates C-H and C-Cl bonds in radical and ionic reactions, and the chemical shifts in NMR-H1 spectra depend on the inductive effects of the substituents.

Behavior of diastereomers of α,β -dichloro-γ-trifluoropropyltrichlorosilane in high-temperature dehydrochlorination reactions

High-temperature dehydrochlorination of diastereomers of,-dichloro--trifluoropropyltrichlorosilane (,-DCT) occurs through a radical mechanism, forming trans-olefin.