Paper
The dehydration of fermentative 2,3‐butanediol into methyl ethyl ketone
Published Feb 20, 1987 · A. Tran, R. P. Chambers
Biotechnology and Bioengineering
72
Citations
1
Influential Citations
Abstract
A solid acid catalyst consisted of sulfonic groups covalently bound to an inorganic matrice was developed to dehydrate 2,3‐butanediol into methyl ethyl ketone. Rate constant and apparent activation energy of the dehydration reaction were determined. The decay course of the catalyst was a two‐stage curve. The catalyst was deactivated more rapidly in the first stage than in the second stage. The strategy of maintaining constant degree of dehydration was employed to lengthen the lifetime of catalyst. Treatment of the 2,3‐butanediol containing fermentation broth with activated carbon greatly facilitated the subsequent dehydration reaction.
The solid acid catalyst developed can effectively dehydrate 2,3-butanediol into methyl ethyl ketone, with a two-stage decay course and maintaining constant dehydration to extend catalyst lifetime.
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