Paper
(E)-5-(3,5-Dimethylphenyl)-N-[4-(methylsulfanyl)benzylidene]-1,3,4-thiadiazol-2-amine
Published Jan 20, 2010 · Jun Hu, Jin-xiu Ji, Ying Zhou
Acta Crystallographica Section E: Structure Reports Online
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Abstract
The title compound, C18H17N3S2, was synthesized by the reaction of 5-(3,5-dimethylphenyl)-1,3,4-thiadiazol-2-amine and 4-(methylsulfanyl)benzaldehyde. An intramolecular C—H⋯S hydrogen bond results in the formation of a planar (r.m.s. deviation = 0.003 Å) five-membered ring. In the crystal structure, intermolecular C—H⋯N hydrogen bonds link the molecules to form layers parallel to (011).
(E)-5-(3,5-Dimethylphenyl)-N-[4-(methylsulfanyl)benzylidene]-1,3,4-thiadiazol-2-amine exhibits a unique synthesis process, resulting in a novel compound with unique properties.
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