Paper
Highly softened polyurethane elastomer synthesized with novel 1,2-bis(isocyanate) ethoxyethane
Published Mar 27, 2004 · K. Kojio, T. Fukumaru, M. Furukawa
Macromolecules
83
Citations
0
Influential Citations
Abstract
A novel diisocyanate, 1,2-bis(isocyanate)ethoxyethane (TEGDI), whose backbone is ether bonds was used for the preparation of polyurethane elastomers (PUEs). 1,6-Hexamethylene diisocyanate (HDI) was also used as a control. The PUEs were prepared with either TEGDI or HDI, poly(oxytetramethylene) glycol (PTMG), and curing agent by a prepolymer method. Differential scanning calorimetry, infrared spectroscopy, and wide-angle X-ray diffraction revealed that the phase separation of the network TEGDI-based PUEs was much weaker compared with that of the HDI ones. Highly softened TEGDI-based PUEs were successfully prepared on account of flexibility of TEGDI itself and weaker phase separation.
Highly softened polyurethane elastomers were successfully prepared using novel 1,2-bis(isocyanate)ethoxyethane (TEGDI) due to its flexibility and weaker phase separation compared to 1,6-hexamethylene diisocyanate (HDI).
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