Interface Reduction Synthesis of H2V3O8 Nanobelts–Graphene for High-Rate Li-Ion Batteries
Cuiping Zhang, Huanqiao Song, Changkun Zhang
May 12, 2015
Citations
26
Citations
Journal
Journal of Physical Chemistry C
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Semantic Scholar
Key Takeaway Key Takeaway: H2V3O8 nanobelts-graphene composites effectively combine the advantages of both materials for high-rate Li-Ion batteries, with a discharge capacity of 246 mAh/g at a current density of 0.5 A.
Abstract
Layer-structured vanadium oxides are one of the most promising cathode intercalation materials for the next generation of lithium-ion batteries (LIBs) because of their high specific capacity, abundant sources, and low cost. Their widespread commercialization is, however, hindered by the fact that most vanadium oxides suffer from low electrical conductivity and poor cycling stability. We synthesized the sandwich composites of H2V3O8 nanobelts and reduced graphene oxide (H2V3O8-rGO) which synergistically combine the advantages of both materials for lithium ion intercalation. Further, we investigated the growth process of the H2V3O8-rGO composites and propose an adsorption–nucleation–reduction–recrystallization mechanism. In the study, graphene oxide played multiple roles: (a) reducing agent to enable the direct surface growth of H2V3O8 nanobelts, (b) providing intimate conducting pathways, and (c) structural stabilizer. A discharge capacity of 246 mAh/g was obtained for the composite at a current density of...