Paper
On the mechanism of hydroesterification of styrene using an in situ-formed cationic palladium complex
Published Apr 20, 2000 · A. Seayad, S. Jayasree, K. Damodaran
Journal of Organometallic Chemistry
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Abstract
Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.
Highly CitedStudy Snapshot
The mechanism of hydroesterification of styrene using in situ-formed cationic palladium complexes involves the formation of palladium hydride species, as confirmed by 31 P-NMR experiments.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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References
Hydroesterification of styrene using an in situ formed Pd(OTs)2(PPh3)2 complex catalyst
Hydroesterification of styrene to 3-phenyl propionate 1 and 2-phenyl propionate 2 using a Pd(OTs)2(PPh3)2 catalyst is efficient and selective, with hydrogen, p-tsa, and water enhancing catalytic activity.
2000·56citations·A. Seayad et al.·Journal of Molecular Catalysis A-chemical
Journal of Molecular Catalysis A-chemical
Comparative investigation of the regioselectivity in styrene and α-methylstyrene hydroalkoxycarbonylation as a function of palladium catalyst structure
The hydrido route is active in styrene and -methylstyrene hydroalkoxycarbonylation, with catalyst and substrate structure strongly influencing regioselectivity.
1999·10citations·Csilla Benedek et al.·Journal of Organometallic Chemistry
Journal of Organometallic Chemistry
Studies Relevant to Palladium-Catalyzed Carbonylation Processes. Mechanisms of Formation of Esters and Amides from Benzylpalladium and (Phenylacetyl)palladium Complexes on Reactions with Alcohols and Amines
Palladium-catalyzed carbonylation reactions can yield amides and esters, with faster amide formation when more basic secondary amines are used.
1998·62citations·Yong‐Shou Lin et al.·Organometallics
Organometallics
Catalytic carbonylation of α-(6-methoxyl-2-naphthyl)ethanol to methyl esters of naproxen using PdCl2–CuCl2–PPh3–acid catalyst system
-(6-methoxyl-2-naphthyl)ethanol can be carbonylated to naproxen methyl esters with up to 100% yield and selectivity using the PdCl2–CuCl2–PPh3 catalyst system without halogen promoters or extreme
1998·15citations·Hongying Zhou et al.·Journal of Organometallic Chemistry
Journal of Organometallic Chemistry
Regioselective hydroesterification of styrene catalyzed by cationic palladium(II) complexes under mild conditions
Cationic palladium(II) complexes effectively catalyze regioselective hydroesterification of styrene under mild conditions, producing branched ester in excellent yield at ambient temperature.
1997·68citations·S. Oi et al.·Journal of Molecular Catalysis A-chemical
Journal of Molecular Catalysis A-chemical
Citations
DFT Investigation of the Mechanism of Methoxycarbonylation of Styrene by Palladium Chloride
The methoxycarbonylation of styrene by palladium chloride involves a two-step mechanism, with methanol undergoing oxidative addition and reductive elimination to form the ester.
2024·0citations·S. Patra et al.·Chemistry
Chemistry
HYDROETHOXYCARBONYLATION OF CYCLOPENTENE IN THE PRESENCE OF A THREE-COMPONENT PdCl2(PPh3)2-PPh3-AlCl3 SYSTEM
Carbon monoxide-based synthesis offers promising alternatives to traditional hydrocarbon raw materials and rising petroleum costs, with potential for future applications in organic synthesis.
2023·0citations·G. Zhaksylykova et al.·Neft i Gaz
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Porous organic polymer-supported palladium catalyst for hydroesterification of olefins
The porous organic polymer-supported palladium catalyst shows excellent hydroesterification performance, adaptability, and recyclability, offering potential for industrial applications.
2020·17citations·Miaomiao Chen et al.·Molecular Catalysis
Molecular Catalysis
Pd-catalyzed alkoxycarbonylation of alkenes promoted by H2O free of auxiliary acid additive
Water effectively improves the catalytic performance of Pd-catalyzed alkoxycarbonylation of alkenes, resulting in a 97% yield and moderate to good generality for various alkenes with alcohols.
2020·11citations·Wen-Yu Liang et al.·Molecular Catalysis
Molecular Catalysis
Synthesis of methyl β-alkylcarboxylates by Pd/diphosphine-catalyzed methoxycarbonylation of methylenealkanes RCH2CH2C(R)=CH2
Pd/diphosphine-catalyzed methoxycarbonylation of synthetically available methylenealkanes effectively synthesizes branched carboxylic acids with high potential for practical application.
2019·17citations·I. Nifant’ev et al.·Applied Catalysis A: General
Applied Catalysis A: General
Hydrocarbomethoxylation of Cyclohexene Catalyzed by Pd(OAc)2-PPh3-p-Toluenesulfonic Acid. Some Aspects of Reaction Kinetics and Thermodynamics of Ligand Exchange between Palladium Complexes
The rate of hydrocarbomethoxylation of cyclohexene with Pd(OAc)2-PPh3-p-Toluenesulfonic acid is influenced by PPh3 concentration, with equilibrium at 373 K.
2019·0citations·N. T. Sevost’yanova et al.·Russian Journal of Physical Chemistry B
Russian Journal of Physical Chemistry B
Развитие науки и образования
Intellectual capital is a public good that should be financed by the state to promote innovative development in all spheres of society, particularly in poor countries.
2018·56citations·Aleksandr Aleksandrovich Razumov et al.