Paper
Palladium (II)-catalyzed alternating copolymerization of alkenes with sulfur dioxide
Published Apr 2, 1998 · L. M. Wojcinski, M. Boyer, Ayusman Sen
Inorganica Chimica Acta
Q2 SJR score
14
Citations
0
Influential Citations
Abstract
Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.
Study Snapshot
Cationic palladium(II) complexes catalyze the alternating copolymerization of alkenes with sulfur dioxide, producing high-melting solids with unique alkene-SO2 structures.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
Full text analysis coming soon...
References
Palladium complex catalysed synthesis of sulfinic acids, sulfinic acid esters, sulfonic acids and S-alkyl alkanethiosulfonates
The novel hydrosulfination reaction, using palladium complexes, effectively synthesizes sulfinic acids, sulfinic acid esters, sulfonic acids, and S-alkyl alkanethiosulfonates from olefins,
1994·15citations·J. Herwig et al.·Inorganica Chimica Acta
Inorganica Chimica Acta
Mechanistic aspects of metal-catalyzed alternating copolymerization of olefins with carbon monoxide
Metal-catalyzed copolymerization of olefins with carbon monoxide offers lower pressures, lower temperatures, and high molecular weights compared to other methods.
1993·262citations·Ayusman Sen·Accounts of Chemical Research
Accounts of Chemical Research
Citations
One-pot synthesis of sulfones via Ni(II)-catalyzed sulfonylation of boronic acids, Na2S2O5 and benzylic ammonium salts
This one-pot nickel-catalyzed synthesis efficiently produces diverse sulfones from readily available boronic acids, sodium metabisulfite, and benzylic ammonium salts, with the intermediate sulfinate isolated.
2021·7citations·Haibo Zhu et al.·Molecular Catalysis
Molecular Catalysis
Palladium-Catalyzed Domino Heck/Sulfination: Synthesis of Sulfonylated Hetero- and Carbocyclic Scaffolds Using DABCO-Bis(sulfur dioxide).
This Pd-catalyzed domino Heck/SO2 insertion reaction effectively synthesizes diverse hetero- and carbocyclic scaffolds using DABSO, a safe and easy-to-handle alternative to SO2 gas, with good yields and scalability.
2021·17citations·Jonathan Bajohr et al.·Organic letters
Organic letters
Activation of SO2 by N/Si+ and N/B Frustrated Lewis Pairs: Experimental and Theoretical Comparison with CO2 Activation.
SO2 activation by N/Si+ and N/B frustrated Lewis pairs shows structural similarities with CO2 activation, with the Lewis acidic moiety playing a key role in the relative stabilities of the adducts.
2019·12citations·A. Adenot et al.·Chemistry
Chemistry
The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry
Sulfur dioxide surrogates have successfully overcome the toxic nature of SO2 in synthetic organic chemistry, enabling new reactions and transformations.
2015·236citations·Edward J. Emmett et al.·Asian Journal of Organic Chemistry
Asian Journal of Organic Chemistry
Fixation of sulfur dioxide into small molecules.
Recent advances in sulfur dioxide insertion into small molecules under transition metal catalysis or metal-free conditions show promise for sulfonyl-derived functional groups in various products.
2015·172citations·Gang Liu et al.·Organic & biomolecular chemistry
Organic & biomolecular chemistry