Paper
Study of Kinetics of Isoprene Polymerization in the Presence of Neodymium-Containing Catalytic Systems Modified in Turbulent Flows
Published Jan 1, 2021 · E. Miftakhov, I. Nasyrov, S. Mustafina
Russian Journal of Applied Chemistry
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Abstract
Abstract The results of studying the kinetics of the polyisoprene synthesis in the presence of neodymium-containing catalytic systems under conditions of preliminary hydrodynamic action at the stage of preparation of the catalytic complex are reported. Mathematical research methods allow expansion of the results of laboratory studies to the scale of continuous industrial production and evaluating the effect of dosages of triisobutylaluminum and diisobutylaluminum hydride on the molecular characteristics of the resulting product. The essential role of triisobutylaluminum, which is initially present in the composition of the catalytic complex, has been demonstrated in the mechanism of limiting the growth of polymer chains.
Isoprene polymerization in neodymium-containing catalytic systems in turbulent flows is influenced by triisobutylaluminum, which plays a crucial role in limiting chain growth and improving molecular characteristics of the resulting product.
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