Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels

doi:10.1039/P19950000839

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Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels

N. Selvakumar, S. Janaki, K. Pramod

1995

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Journal

Journal of The Chemical Society-perkin Transactions 1

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Key Takeaway

Key Takeaway: The novel sesquiterpenes 1 and 2 from Eremophila georgei diels were successfully synthesized using a bicyclo[3.2.1]octane framework and a bicyclo[2.2.2]octane derivative.

Abstract

The first stereoselective total synthesis of the novel sesquiterpenes 1 and 2 is described. The preparation of the key intermediate 27 involved a rearrangement of a bicyclo[3.2.1]octane framework to an isomeric bicyclo[3.2.1]octene skeleton via a bicyclo[2.2.2]octane derivative.

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