Synthesis of Pt compounds containing chiral (2S,4S)-pentane-2,4-diyl-bis(5H-dibenzo[b]phosphindole) as ligand and their use in asymmetric hydroformylation of styrene derivatives

doi:10.1016/S0022-328X(97)00130-7

Paper

DOI: 10.1016/S0022-328X(97)00130-7

Synthesis of Pt compounds containing chiral (2S,4S)-pentane-2,4-diyl-bis(5H-dibenzo[b]phosphindole) as ligand and their use in asymmetric hydroformylation of styrene derivatives

Published Aug 1, 1997 · I. Tóth, C. Elsevier, J. G. Vries

Journal of Organometallic Chemistry

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Pt compounds containing chiral (2S,4S)-pentane-2,4-diyl-bis(5H-dibenzo[b]phosphindole) as ligand show promising potential for asymmetric hydroformylation of styrene derivative

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Citations

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Coordination chemistry of ligands bearing heavy group 14 and 15 elements: Comparative analysis of their influence on transition metal chemistry

Ligands containing heavy group 14 and 15 elements show distinct chemical properties and distinct reactivity compared to lighter counterparts in transition metal catalysis.

2025·0citations·Yeong Jun Son et al.·Coordination Chemistry Reviews

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Organodiphosphines in cis-Pt(η2-PXnP)(Cl)2 (n = 1,2,3) derivatives: Structural aspects

This paper presents 130 Pt(ii) complexes with organodiphosphines, highlighting their diverse structural features and potential for distortion and ligand isomerism.

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Phosphole-based ligands in catalysis

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Recent advances in heterobimetallic catalysis across a "transition metal-tin" motif.

Transition metal-tin catalysts show promise for diverse organic transformations, including Friedel-Crafts alkylation, carbonylation, polymerization, cyclization, olefin metathesis, Heck coupling, hydroarylation, Michael addition, and tandem coupling.

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Synthesis of hemilabile P,N-ligands with a pentane-2,4-diyl backbone

A two-step synthetic method allows for the synthesis of enantiomerically pure pentane-2,4-diyl based P,N-ligands with a highly tunable structure, useful in asymmetric catalytic syntheses.

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Organodiphosphines are useful as soft P,P′ donor ligands in platinum chemistry, with cis derivatives dominating and their bond distances varying between 2.270 and 2.348.

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Stabilization of an Intramolecularly Coordinated Stannylidenium Cation

The complex [2, 6-(Me2NCH2)2C6H3]SnPt(-pyt)2I] was synthesized by treating trans-[2, 6-(Me2NCH2)2C6H3]SnI2PtI2

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