New Thiadiazole Dioxide Bridging Ligand with a Stable Radical Form for the Construction of Magnetic Coordination Chains

doi:10.1021/CG500906W

beta

New Thiadiazole Dioxide Bridging Ligand with a Stable Radical Form for the Construction of Magnetic Coordination Chains

D. Pinkowicz, Zhanyong Li, P. Pietrzyk

Aug 21, 2014

Citations

Journal

Crystal Growth & Design

Full text

Semantic Scholar

Key Takeaway

Key Takeaway: The new thiadiazole dioxide-type bridging ligand can form stable anionic radicals and chelate two metal centers in a symmetric fashion, enabling the construction of magnetic coordination chains.

Abstract

A new thiadiazole dioxide-type bridging ligand with the ability to form stable anionic radicals and the ability to chelate two metal centers in a symmetric fashion has been designed, synthesized, and fully characterized. Its paramagnetic potassium salt and an example of a CuII coordination chain were also obtained.

Text copied to clipboard

copied to clipboard