Paper
A mixed anhydride approach to the preparation of sulfinate esters and allylic sulfones: Trimethylacetic p-toluenesulfinic anhydride
Published Aug 2, 2017 · E. Jacobsen, Mihir K. Chavda, Kokou M. Zikpi
Tetrahedron Letters
Q3 SJR score
9
Citations
0
Influential Citations
Abstract
Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.
Study Snapshot
The study presents a novel method for preparing sulfinate esters and allylic sulfones using a mixture of toluenesulfinic acid and trimethylacetyl chloride.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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References
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Citations
Strategies for the direct oxidative esterification of thiols with alcohols
Oxidative esterification of thiols with alcohols can produce sulfinic esters and sulfonic ester derivatives, offering potential applications in organic synthesis and pharmacology.
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Synthesis
Electrochemical Synthesis of Sulfinate Esters: Nickel(II)-Catalyzed Oxidative Esterification of Thiols with Alcohols in an Undivided Cell
Nickel-catalyzed electrochemical oxidative esterification of thiols with alcohols allows for the convenient, one-pot synthesis of sulfinate esters from thiols.
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ACS Omega
Modern Stereoselective Synthesis of Chiral Sulfinyl Compounds
Modern methods for preparing chiral sulfinyl compounds in enantiopure or enantiomerically enriched form offer potential for asymmetric synthesis and drug design.
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This study demonstrates a room-temperature, 1.5-h process for synthesising sulfinamides with 32-83% yields using organometallic reagents, sulfur dioxide, and nitrogen-based nucleophiles.
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The Journal of Organic Chemistry
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This study presents a new method for asymmetric synthesis of allylic sulfones with quaternary stereocenters, enabling the synthesis of complex molecules with high regio- and enantioselectivity.
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Angewandte Chemie
Efficient Synthesis of Sulfinate Esters and Sulfinamides via Activated Esters of p-Toluenesulfinic Acid
Using carbodiimide EDC for selective synthesis of sulfinate esters and EDC-HCl for sulfinamides is the most efficient pathway for synthesis of these compounds.
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Photoinduced synthesis of allylic sulfones using potassium metabisulfite as the source of sulfur dioxide
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