Anomale Reaktionsweise eines 3-Chlor-2-nitroanisols

doi:10.1002/CBER.19801130624

Paper

Anomale Reaktionsweise eines 3-Chlor-2-nitroanisols

Published Jun 1, 1980 · W. Ried, Günther Sell

Chemische Berichte

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Abstract

Anomalous Reaction of a 3-Chloro-2-nitroanisole During the synthesis of 8-chloro-1,5-dihydro-5-hydroxy-1-phenyl-2H-1,5-benzodiazepine-2,4 (3H)-dione (4) 3,5-dichloro-2-nitroanisole (B) reacts with aniline under cleavage of the etherlinkage to form 5-chloro-3-hydroxy-2-nitrodiphenylamine (1).

Study Snapshot

During the synthesis of 8-chloro-1,5-dihydro-5-hydroxy-1-phenyl-2H-1,5-benzodiazepine-2,4 (3H)-dione (4), 3,5-dichloro-2-nitroanisole (B) spontaneously reacts with

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

Paper

Anomale Reaktionsweise eines 3-Chlor-2-nitroanisols

References

1,4-benzodiazepines. Chemistry and some aspects of the structure-activity relationship.

1,4-benzodiazepines are readily accessible and exhibit favorable tranquilizing and toxic properties, with their structure-activity relationship influenced by the type and position of substituents.

Citations

Notiz über eine unerwartete Reaktion eines Disulfids

Diethyl o,o′-dithiobis(phenylcarbamoylacetate) (1) is converted into ethyl 3-oxo-3,4-dihydro-2H-1,4-benzothiazine-2-carboxylate (2) by sodium hydrogen

Notiz über das ungewöhnliche Verhalten von 2,3,4,5-Tetrahydro-1,5-benzothiazepin-4-onen bei der Arylierung

Arylation of 2,3,4,5-tetrahydro-1,5-benzothiazepin-4-ones can produce diaryl sulfides 4a, b, and 5 in some reactions, highlighting the unusual behavior of these compounds during arylation.