A New Application of Dimethyl Trithiocarbonate. Methylthiothiocarbonylation of 2,4-Pentanedione and Some β-Oxoesters

doi:10.1080/00397919808004445

Paper

DOI: 10.1080/00397919808004445

A New Application of Dimethyl Trithiocarbonate. Methylthiothiocarbonylation of 2,4-Pentanedione and Some β-Oxoesters

Published Sep 1, 1998 · A. Oliva, A. Molinari, L. Sanchez

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Abstract

Abstract 2,4-Pentanedione, ethyl acetoacetate, benzoyl acetate and diethyl malonate 1a-d react with sodium acetate and dimethyl trithiocarbonate in dimethylformamide to afford methyl-β,β′-dicarbonyldithiocarboxylate derivatives 2a-d in moderate yield.

Study Snapshot

Dimethyl trithiocarbonate can be used to produce methyl-,′-dicarbonyldithiocarboxylate derivatives from 2,4-pentanedione and some -oxoesters in moderate yield.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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