Application of 1‐(3‐Bromo‐3,3‐difluoroprop‐1‐ynyl)benzenes in Diels—Alder Reactions: Synthesis of ortho‐CF2Br‐Substituted Biaryls.

doi:10.1002/CHIN.200904071

Paper

Application of 1‐(3‐Bromo‐3,3‐difluoroprop‐1‐ynyl)benzenes in Diels—Alder Reactions: Synthesis of ortho‐CF2Br‐Substituted Biaryls.

Published Jan 27, 2009 · V. M. Muzalevskiy, V. Nenajdenko, A. V. Shastin

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Abstract

Application of 1-(3-Bromo-3,3-difluoroprop-1-ynyl)benzenes in Diels–Alder Reactions: Synthesis of ortho-CF2Br-Substituted Biaryls Biaryls with an ortho-CF2Br Group Vasiliy M. Muzalevskiy, a Valentine G. Nenajdenko,*a Aleksey V. Shastin,b Elizabeth S. Balenkova,a Günter Haufe*c a Department of Chemistry, Moscow State University, Leninskie Gory, Moscow 119992, Russian Federation E-mail: nen@acylium.chem.msu.ru b Institute of Problems of Chemical Physics, Chernogolovka, Moscow Region 142432, Russian Federation E-mail: shastin@icp.ac.ru c Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Correnstr. 40, 48149 Münster, Germany Fax +49(251)8339772; E-mail: haufe@uni-muenster.de Received 26 March 2008; revised 21 May 2008

Study Snapshot

Ortho-CF2Br-substituted biaryls can be synthesized using 1-(3-Bromo-3,3-difluoroprop-1-ynyl)benzenes in Diels-Alder reactions, providing a new route for the synthesis of

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Application of 1‐(3‐Bromo‐3,3‐difluoroprop‐1‐ynyl)benzenes in Diels—Alder Reactions: Synthesis of ortho‐CF2Br‐Substituted Biaryls.

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