Oxidative Arylation of Ethylene with Benzene to Produce Styrene

doi:10.1246/CL.2000.1064

Paper

Oxidative Arylation of Ethylene with Benzene to Produce Styrene

Published Sep 1, 2000 · Takaya Matsumoto, H. Yoshida

Chemistry Letters

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Abstract

Rh complexes were found to work as catalysts for oxidative arylation of ethylene with benzene to produce styrene by addition of acetylacetone and O2 without any oxidizing agent like Cu salt. Vinylacetate was not formed at all in spite of coexistence of acetic acid.

Study Snapshot

Rh complexes can act as catalysts for oxidative arylation of ethylene with benzene to produce styrene without needing an oxidizing agent like Cu salt.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

Paper

Oxidative Arylation of Ethylene with Benzene to Produce Styrene

References

Citations

Oxidative coupling of N-nitrosoanilines with substituted allyl alcohols under rhodium (III) catalysis

Rhodium(III) catalysis efficiently synthesizes functional N-nitroso ortho -aryl aldehydes and ketones with low catalyst loading, high functional group tolerance, and superior reactivity of allyl alcohols towards N-nitrosoanilines.

Pd(II) and Rh(I) Catalytic Precursors for Arene Alkenylation: Comparative Evaluation of Reactivity and Mechanism Based on Experimental and Computational Studies.

Pd catalysis produces styrene more rapidly than Rh, with Pd being more selective for arene/olefin coupling, while Rh catalysis is more selective for arene/olefin coupling.

Electron-Deficient Ru(II) Complexes as Catalyst Precursors for Ethylene Hydrophenylation

Electron-deficient Ru(II) complexes show potential for catalytic benzene ethylation, with (Ttz)Ru(NCMe)(P(OCH2)3CEt)Ph showing the highest activity.

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The Pd@d-C 3N4 catalyst effectively synthesizes styrene from benzene and ethylene in a single-step, improving the commercial styrene production process.

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