Breakthrough synthesis of 2,3,3,3-tetrafluoropropene via hydrogen-assisted selective dehydrochlorination of 1,1,1,2-tetrafluoro-2-chloropropane over nickel phosphides

doi:10.1016/j.jcat.2020.08.022

Paper

Breakthrough synthesis of 2,3,3,3-tetrafluoropropene via hydrogen-assisted selective dehydrochlorination of 1,1,1,2-tetrafluoro-2-chloropropane over nickel phosphides

Published Aug 28, 2020 · Song Tian, W. Mao, Pengfei Sun

Journal of Catalysis

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Abstract

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Study Snapshot

Ni 3 P catalysts show higher activity and HFO-1234yf selectivity in hydrogen-assisted selective dehydrochlorination of 1,1,1,2-tetrafluoro-2-chloropropane, leading to a breakthrough synthesis of 2,3,3,3-tetrafluoroprop

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

Breakthrough synthesis of 2,3,3,3-tetrafluoropropene via hydrogen-assisted selective dehydrochlorination of 1,1,1,2-tetrafluoro-2-chloropropane over nickel phosphides

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References

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Desulfurization of 2-phenylcyclohexanethiol over transition-metal phosphides

MoP and WP are more active than Ni 2 P in desulfurizing 2-phenylcyclohexanethiol, with -elimination dominating over Ni 2 P and hydrogenolysis as fast as -elimination over MoP and WP.

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Microwave assisted combustion of phytic acid and nickel nitrate produces Ni2P@C, a robust catalyst for hydrodechlorination of HCFC-22, offering a versatile method for synthesis of carbon-encapsulated metal phosphide particles.

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Adding NiF2 to FeF2 cathodes in lithium-ion batteries can boost capacity, but may accelerate capacity fading.

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Pd 3 P 0.95 /SiO 2 catalysts show higher aqueous phase hydrodechlorination rates and better sulfide resistance than Pd/SiO 2 catalysts, offering better stability in the 4-chlorophenol hydrodechlorination process.

Ultradispersed Nickel Phosphide on Phosphorus-Doped Carbon with Tailored d-Band Center for Efficient and Chemoselective Hydrogenation of Nitroarenes

Ultradispersed Nickel Phosphide on Phosphorus-Doped Carbon with Tailored d-Band Center for Efficient and Chemoselective Hydrogenation of Nitroarenes

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Supported Ni2P/Ni12P5 nanoparticles show high selectivity for chemoselective hydrogenation of acetophenone, resulting in 1-phenylethanol, with potential applications in various chemical processes.

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