Paper
Cerium(IV)-induced decarboxylation of penta-ammineoxaloacetatocobalt(III) perchlorate
Published Jan 1, 1988 · K. Subramani, V. S. Srinivasan
Journal of The Chemical Society-dalton Transactions
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Abstract
Cerium(IV) induces electron transfer in penta-ammineoxaloacetatocobalt(III) perchlorate, yielding CO2 and cobalt(II) quantitatively as ultimate products due to carbon–carbon bond fission. Enzymatic decarboxylation of oxaloacetic acid yields only pyruvic acid, whereas cerium(IV) oxidises oxaloacetic acid to CO2, probably because of radical intervention.
Study Snapshot
Cerium(IV)-induced decarboxylation of penta-ammineoxaloacetatocobalt(III) perchlorate yields CO2 and cobalt(II) as products, while enzymatic decarboxylation of oxaloacetic
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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