Paper
Unprecedented Cesium and Potassium Fluorides Catalyzed Trialkylsilylation and Tributylstannylation of Terminal Alkynes with Trifluoromethyl-Trialkylsilanes and -Tributylstannane
Published Nov 3, 2000 · M. Ishizaki, O. Hoshino
Tetrahedron
Q3 SJR score
23
Citations
0
Influential Citations
Abstract
Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.
Study Snapshot
Cesium and potassium fluorides catalyze trialkylsilylation and tributylstannylation of terminal alkynes with trifluoromethyl-trialkylsilanes and -tributylstannane, producing high yields of 1-silyl- and
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
Sign up to use Study Snapshot
Consensus is limited without an account. Create an account or sign in to get more searches and use the Study Snapshot.
Full text analysis coming soon...
References
Versatile cyclisation reactions using selenoboranes
Selenoboranes can be used for versatile cyclisation reactions, enabling the synthesis of heterocycles, carbocycles, and -kainoid derivatives.
1993·17citations·T. Kataoka et al.·Journal of The Chemical Society-perkin Transactions 1
Journal of The Chemical Society-perkin Transactions 1
Intramolecular reactions of N-nitrenes with alkynes: conformational anchoring in spiro-fused 2H-azirines
N-nitrenes can form spiro-fused 2H-azirines with unique conformational anchoring properties, potentially aiding in drug discovery and pharmacological research.
1986·30citations·R. S. Atkinson et al.·Journal of The Chemical Society-perkin Transactions 1
Journal of The Chemical Society-perkin Transactions 1
The protection of terminal ethynyl groups in Grignard syntheses
Trimethylsilyl groups can effectively protect terminal ethynyl groups in Grignard syntheses, enabling the preparation of compounds with improved properties.
1967·11citations·C. Eaborn et al.·Journal of The Chemical Society C: Organic
Journal of The Chemical Society C: Organic
Citations
Click and Cut: a click chemistry approach to developing oxidative DNA damaging agents
This study presents a click chemistry strategy for developing DNA damaging metallodrugs, resulting in a high-affinity copper(II) binding agent with potent DNA recognition and damaging properties.
2021·10citations·N. McStay et al.·Nucleic Acids Research
Nucleic Acids Research
Fluoride anion-initiated bis-trifluoromethylation of phenyl aromatic carboxylates with (trifluoromethyl)trimethylsilane.
This study demonstrates a fluoride anion-initiated reaction for the formation of O-silyl-protected 2-aryl-1,1,1,3,3,3-hexafluoroisopropanols, with various functional groups tolerated for further elaboration.
2020·1citation·Kenjiro Takahashi et al.·Chemical communications
Chemical communications
Deprotonative Silylation of Aromatic C-H Bonds Mediated by a Combination of Trifluoromethyltrialkylsilane and Fluoride.
This study developed a method for deprotonative silylation of aromatic C-H bonds using trifluoromethyltrimethylsilane and fluoride, which can be applied to the synthesis of bioactive synthetic retinoid analogs.
2017·16citations·Kanako Nozawa‐Kumada et al.·The Journal of organic chemistry
The Journal of organic chemistry
Nucleophilic Additions of Perfluoroalkyl Groups
Nucleophilic perfluoroalkyl reagents have significant properties and applications in agrochemistry, drug design, and material chemistry, with potential for future applications.
2016·6citations·P. Beier et al.·Organic Reactions
Organic Reactions
Synthesis of triazolyl-linked polysialic acids
This study developed a new method for synthesis of triazolyl-linked oligosialic acids, which may be useful in preparing biologically important oligosialic acid analogues.
2014·7citations·Decai Xiong et al.·Tetrahedron
Tetrahedron
NHC catalysed trimethylsilylation of terminal alkynes and indoles with Ruppert's reagent under solvent free conditions
This organo-catalytic method effectively enables the trimethylsilylation of terminal alkynes and indoles under solvent-free conditions, with excellent yields and chemospecific N-silylation of indoles.
2014·18citations·Panjab Arde et al.·RSC Advances
RSC Advances
Synthesis of amino-substituted indanes and tetralins via consecutive multibond-forming tandem processes.
This study developed a rapid and general approach for the synthesis of amino-substituted indanes and tetralins from readily available alkyne-derived allylic alcohols, resulting in diverse libraries of C-1 amino-substituted indanes and te
2013·27citations·Mark W. Grafton et al.·The Journal of organic chemistry
The Journal of organic chemistry
Iron-catalyzed formation of 2-aminopyridines from diynes and cyanamides.
Iron-catalyzed cycloaddition efficiently forms highly substituted 2-aminopyridines in a high yielding and regioselective manner, with potential applications in synthesis of pharmaceuticals and nutraceuticals.
2012·61citations·T. Lane et al.·The Journal of organic chemistry
The Journal of organic chemistry
Hydrogen‐Bond‐Assisted Helical Folding of Propeller‐Shaped Molecules: Effects of Extended π‐Conjugation on Chiral Selection, Conformational Stability, and Exciton Coupling
Extended -conjugation in propeller-shaped molecules significantly affects their stabilities and steric bias, enabling precise control of structural folding and chiral center configurations.
2012·8citations·Elizabeth A. Opsitnick et al.·European Journal of Organic Chemistry
European Journal of Organic Chemistry