Paper
Chemistry of 2,4,6-trinitrobenzonitrile. 1. Nitro group substitution in 2,4,6-trinitrobenzonitrile under the action of anionic nucleophiles. Factors favoring substitution of the ortho-nitro group
Published Dec 1, 2001 · I. Dalinger, T. I. Cherkasova, S. Vorobev
Russian Chemical Bulletin
Q3 SJR score
5
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0
Influential Citations
Abstract
The direction of the nitro group substitution (the ratio of the ortho/para substitution) in 2,4,6-trinitrobenzonitrile under the action of anionic nucleophiles (MeO–, RS–, and N3–) as well as of HCl was studied. The factors favoring ortho substitution were revealed.
Study Snapshot
The ortho-nitro group substitution in 2,4,6-trinitrobenzonitrile is favored by anionic nucleophiles and HCl, with the ratio of ortho/para substitution favoring ortho substitution.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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Acidity scales in dimethyl sulfoxide solution and NMP allow direct comparisons with H20 and gas-phase pKa values, providing insights into solvation effects.
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Problems of Trotyl (TNT) Processing into Condensation Monomers, Polymers and Dyes
Trotyl (TNT) processing into condensation monomers, polymers, and dyes is a complex process, requiring advanced technology and expertise to effectively address the challenges of utilizing this explosive component in ammunition.
1997·10citations·V. A. Tartakiovsky et al.
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