Paper
Photochemical Cleavage of Benzylic C-N Bond To Release Amines.
Published Jun 9, 2016 · Pengfei Wang, Dattatray A. Devalankar, Wenya Lu
The Journal of organic chemistry
Q2 SJR score
19
Citations
0
Influential Citations
Abstract
The 3-(diethylamino)benzyl (DEABn) group has been studied for releasing primary, secondary, and tertiary amines by direct photochemical breaking of the benzylic C-N bond. While photochemical release of primary and secondary amines provides high yields in methanol, release of tertiary amines in MeCN/water can improve yields and reduce the undesired dealkylation side reaction.
Study Snapshot
Photochemical breaking of the benzylic C-N bond can release primary, secondary, and tertiary amines, with improved yields and reduced side reactions in MeCN/water.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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