Cobalt(II) and nickel(II) complexes with 1,1-bis(diphenylphosphinomethyl)-1-diphenylphosphino-ethylethane, atriphos, and 1,1,1-tris(diethylphosphinomethyl)ethane, etriphos. Crystal structures of the trinuclear complexes [Co3(atriphos)2Cl6] and [Ni3(etriphos)2Cl6] · 2 CHCl3

doi:10.1016/S0022-328X(00)93593-9

Paper

Cobalt(II) and nickel(II) complexes with 1,1-bis(diphenylphosphinomethyl)-1-diphenylphosphino-ethylethane, atriphos, and 1,1,1-tris(diethylphosphinomethyl)ethane, etriphos. Crystal structures of the trinuclear complexes [Co3(atriphos)2Cl6] and [Ni3(etriphos)2Cl6] · 2 CHCl3

Published Apr 14, 1981 · C. Bianchini, A. Meli, A. Orlandini

Journal of Organometallic Chemistry

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The crystal structures of cobalt(II) and nickel(II) complexes with 1,1-bis(diphenylphosphinomethyl)-1-diphenylphosphino-ethylethane and 1,1-tris(diethylphosphinomethyl)

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

Cobalt(II) and nickel(II) complexes with 1,1-bis(diphenylphosphinomethyl)-1-diphenylphosphino-ethylethane, atriphos, and 1,1,1-tris(diethylphosphinomethyl)ethane, etriphos. Crystal structures of the trinuclear complexes [Co3(atriphos)2Cl6] and [Ni3(etriphos)2Cl6] · 2 CHCl3

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References

Magnetic Investigations of Spin-free Cobaltous Complexes. VI.1 Complexes Containing Phosphines and the Position of Phosphines in the Spectrochemical Series

Phosphines in spin-free cobaltous complexes play a crucial role in determining the magnetic and spectral properties of these complexes, with their position in the spectrochemical series influencing the magnetic and spectral properties of these complexes.

Trimeric nickel(II) complexes with bridging triphosphine ligand 1,1,1-tris(diphenylphosphinoethyl)ethane (etp3). X-ray structure of the complex [Ni3Cl6(etp3)2]·0.7CHCl3

The X-ray structure of the trinuclear nickel(II) complex with bridging triphosphine ligand 1,1,1-tris(diphenylphosphinoethyl)ethane (etp3) shows three four-coordinate nickel ions bridging

Citations

Synthesis and structural characterization of ruthenium(II) complexes bearing phosphine-pyrazolyl based tripod ligands

Phosphine-pyrazolyl based tripod ligands synthesized and characterized in ruthenium(II) complexes show poor to moderate catalytic activity in the transfer hydrogenation of acetophenone.

Chiral Chelate Ligands Based on a Neopentane Framework; Introducing Indenyl and Fluorenyl Donor Groups

Chiral chelate ligands based on a neopentane framework can be synthesized using indenyl and fluorenyl donors, offering potential applications in organic synthesis and catalysis.

Pyrazole as a Donor Function in Neopentane‐Based Tripod Ligands RCH2C(CH2pyrazol‐1‐yl)3–n(CH2PR2)n – Synthesis and Coordination Chemistry

Pyrazole can be used as a donor function in neopentane-based tripod ligands, enabling the synthesis of complex molecules with diverse functionalities.

Reactions Involving Transition-Metal Ions and Tripodal Phosphines and Arsines

Transition metal ions and tripodal ligands often form unique products and exhibit unique structural properties, due to their unique geometric requirements.

Reactivity of the triethylphosphinecarbon disulfide adduct Et3PCS2 toward iron(II) cations in the presence of the bis(tertiary phosphines), depe, and diphos, x-ray crystal structures of the complexes [(depe)2Fe(S2CPEt3)](BPh4)2 and [(depe)2Fe(S2CH)](BPh4)

The triethylphosphinecarbon disulfide adduct Et3PCS2 reacts with iron(II) cations to produce complexes with distorted octahedral geometry, linked to phosphorus atoms in depe molecules and sulfur atoms