Copper catalyzed cross-coupling of iodobenzoates with bromozinc-difluorophosphonate.

doi:10.1021/ol3006425

Paper

Copper catalyzed cross-coupling of iodobenzoates with bromozinc-difluorophosphonate.

Published Mar 21, 2012 · Zhange Feng, Fei Chen, Xingang Zhang

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Abstract

A copper-catalyzed cross-coupling of iodobenzoates with bromozinc-difluorophosphonate, generated from diethyl bromodifluoromethylphosphonate and zinc in dioxane, is reported. The notable features of this reaction are its high reaction efficiency, excellent functional group compatibility, and operational simplicity. This protocol provides a useful and facile access to aryldifluorophosphonates of interest in life science.

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Copper-catalyzed cross-coupling of iodobenzoates with bromozinc-difluorophosphonate offers high reaction efficiency, excellent functional group compatibility, and operational simplicity for accessing aryldifluorophosphonates in life science.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Copper catalyzed cross-coupling of iodobenzoates with bromozinc-difluorophosphonate.

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