Paper
Debenzylation and detritylation by bromodimethylborane: synthesis of mono-acid or mixed-acid 1,2- or 2,3-diacyl-sn-glycerols.
Published Apr 1, 1992 · D. Kodali, R. Duclos
Chemistry and physics of lipids
Q2 SJR score
16
Citations
0
Influential Citations
Abstract
Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.
Study Snapshot
Bromodimethylborane effectively deprotectes primary alcohols, enabling the synthesis of optically pure mono-acid or mixed-acid 1,2- or 2,3-diacyl-sn-glycerols with minimal acyl migration.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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References
A short highly regio- and stereoselective synthesis of triacylglycerols
This study presents a highly regioselective and stereoselective synthesis of triacylglycerols using enantiomerically pure glycidol, enabling the production of (R)- and (S)-lauroyl oleoyl palm
1991·28citations·P. Sonnet·Chemistry and Physics of Lipids
Chemistry and Physics of Lipids
The interfacial conformation and transbilayer movement of diacylglycerols in phospholipid bilayers.
1,2-DLG in egg phosphatidylcholine bilayers forms bilayers with no hexagonal phase separation, and its interfacial conformation resembles that of crystalline 1,2-dilauroyl-sn-glycerol and certain PCs.
1991·96citations·J. Hamilton et al.·The Journal of biological chemistry
The Journal of biological chemistry
Structure and polymorphism of saturated monoacid 1,2-diacyl-sn-glycerols.
1,2-diacyl-sn-glycerols show unique polymorphic behavior, with different packing patterns and chain tilts compared to 1,3-diacyl-glycerols.
1990·32citations·D. Kodali et al.·Biochemistry
Biochemistry
Acyl migration in 1,2-dipalmitoyl-sn-glycerol.
Acyl migration in 1,2-dipalmitoyl-sn-glycerol to 1,3-dipalmitoglycerol occurs at different temperatures and conditions, with the quickest time being 1 - 2 hours in a polar solvent and less than 1 hour on dry silica gel.
1990·138citations·D. Kodali et al.·Chemistry and physics of lipids
Chemistry and physics of lipids
Nucleoside conjugates. 10. Synthesis and antitumor activity of 1-beta-D-arabinofuranosylcytosine 5'-diphosphate-1,2-dipalmitins.
The L and DL isomers of ara-CDP-dipalmitin show promising antitumor activity against ara-C2 resistant L1210 lymphoid leukemia sublines, with potential for improved efficacy.
1988·19citations·C. Hong et al.·Journal of medicinal chemistry
Journal of medicinal chemistry
Synthesis of enantiomerically pure phospholipids including phosphatidylserine and phosphatidylglycerol.
This study presents a new approach for synthesizing enantiomerically pure phospholipids, including phosphatidylserine and phosphatidylglycerol, with high-yield yields.
1988·29citations·P. Woolley et al.·Chemistry and Physics of Lipids
Chemistry and Physics of Lipids
Functions of diacylglycerol in glycerolipid metabolism, signal transduction and cellular transformation.
Diacylglycerol plays a complex role in glycerolipid metabolism, signal transduction, and cellular transformation, with defects in its regulation potentially leading to cellular transformation and growth control issues.
1988·47citations·Bishop Wr et al.·oncogene Research
oncogene Research
Phosphoric acid derivatives. XVI. Phosphatidylglycerols from diacylglycerol (o-acetoxyphenyl hydrogen phosphates)
Phosphatidylglycerols can be synthesized from diacylglycerol by coupling it with 1,2-isopropylideneglycerol and removing the phosphate-protecting and isopropylidene groups.
1988·1citation·J. Calderon et al.·Chemistry and Physics of Lipids
Chemistry and Physics of Lipids
Citations
Conjugation of peptides to short-acyl-chain ceramides for delivery across mucosal cell barriers.
Conjugating peptides to short-acyl-chain ceramides effectively enables their delivery across tight mucosal cell barriers, potentially overcoming oral delivery challenges.
2020·0citations·R. Duclos et al.·Bioorganic & medicinal chemistry letters
Bioorganic & medicinal chemistry letters
Catalytic synthesis of enantiopure mixed diacylglycerols – synthesis of a major M. tuberculosis phospholipid and platelet activating factor.
This novel catalytic one-pot synthesis efficiently synthesizes enantiopure mixed diacylglycerols, enabling the synthesis of major Mycobacterium tuberculosis phospholipids and platelet activating factor.
2013·17citations·P. Fodran et al.·Organic & biomolecular chemistry
Organic & biomolecular chemistry
The preparation of 2-O-[1'-C]arachidonoyl-1-O-stearoyl-sn-glycerol.
This study demonstrates a facile, radiochemically pure, and efficient method for preparing 2-O-[1'-(14)C]arachidonoyl-1-O-stearoyl-sn-glycerol, an endogenous cannabinoid receptor-signaling molecule
2009·3citations·R. Duclos et al.·Journal of labelled compounds & radiopharmaceuticals
Journal of labelled compounds & radiopharmaceuticals
Regioselective and stereospecific acylation across oxirane- and silyloxy systems as a novel strategy to the synthesis of enantiomerically pure mono-, di- and triglycerides.
This study presents a novel strategy for enantiomerically pure synthesis of mono-, di-, and triglycerides using a TBABr-CAA-TMSBr reagent system.
2007·29citations·S. D. Stamatov et al.·Organic & biomolecular chemistry
Organic & biomolecular chemistry
A direct transformation of O-silyl groups into O-trichloroacetates. A novel synthetic approach to protein kinase C ligands: 1-oleoyl-2-acetyl- and 1-hexadecyl-2-acetyl-sn-glycerols
This study presents a novel synthetic approach for producing stereochemically pure 1-oleoyl-2-acetyl- and 1-hexadecyl-2-acetyl-sn-glycerols, which are essential for protein kinase C ligands.
2005·6citations·S. D. Stamatov et al.·Tetrahedron Letters
Tetrahedron Letters