Photocatalytic Decarboxylative Hydroxylation of Carboxylic Acids Driven by Visible Light and Using Molecular Oxygen.

doi:10.1021/acs.joc.6b01360

Paper

Photocatalytic Decarboxylative Hydroxylation of Carboxylic Acids Driven by Visible Light and Using Molecular Oxygen.

Published Jul 18, 2016 · Hai-Tao Song, W. Ding, Quan-Quan Zhou

The Journal of organic chemistry

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48

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0

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Abstract

This paper discloses the first example of photocatalytic direct decarboxylative hydroxylation of carboxylic acids. It enables the conversion of a variety of readily available carboxylic acids to alcohols in moderate to high yields. This unprecedented protocol is accomplished under extremely mild reaction conditions using molecular oxygen (O2) as a green oxidant and using visible light as a driving force.

Study Snapshot

Photocatalytic direct decarboxylative hydroxylation of carboxylic acids enables moderate to high yields of alcohols under mild reaction conditions using molecular oxygen and visible light.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Photocatalytic Decarboxylative Hydroxylation of Carboxylic Acids Driven by Visible Light and Using Molecular Oxygen.

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