Paper
Oxidative Dehydrogenation of Hydrazobenzenes toward Azo Compounds Catalyzed by tert-Butyl Nitrite in EtOH
Published Oct 29, 2020 · Zhiqiang Wang, Jiang-Xi Yu, S. Bai
ACS Omega
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Abstract
We describe a tert-butyl nitrite-catalyzed oxidative dehydrogenation of hydrazobenzenes for producing azobenzenes. This method proceeds at ambient temperature and under an atmospheric environment by employing eco-friendly EtOH as the medium, representing a mild, general route to the synthesis of various symmetrical and nonsymmetrical azobenzenes in excellent yields with broad functional group tolerance.
This study presents a mild, eco-friendly method for synthesis of various azobenzenes using tert-butyl nitrite in EtOH, offering excellent yields and broad functional group tolerance.
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