The disproportionation of cyclohexa-1,3-diene to benzene and cyclohexene catalysed by (cyclohexa-1,3-diene)(pentamethylcyclopentadienyl)rhodium

doi:10.1039/C29690001156

Paper

The disproportionation of cyclohexa-1,3-diene to benzene and cyclohexene catalysed by (cyclohexa-1,3-diene)(pentamethylcyclopentadienyl)rhodium

Published 1969 · K. Moseley, P. Maitlis

Journal of The Chemical Society D: Chemical Communications

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Abstract

(Cyclohexa-1,3-diene)(pentamethylcyclopentadienyl)rhodium, (IIa), is a very active catalyst for disproportionation of cyclohexa-1,3-diene to cyclohexene and benzene, and cyclohexa-1,4-diene is isomerised to the 1,3-isomer during the formation of the complexes (II).

Study Snapshot

This catalyst is a promising tool for the production of cyclohexene and benzene from cyclohexa-1,3-diene, with potential applications in the production of benzene and cyclohexene from cyclohexa-1,3-diene.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

The disproportionation of cyclohexa-1,3-diene to benzene and cyclohexene catalysed by (cyclohexa-1,3-diene)(pentamethylcyclopentadienyl)rhodium

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References

Citations

Rhodium‐Catalyzed Alkene Hydrosilylation via a Hydride Shuttle Process by Diene Ligands: Dramatic Enhancement of Regio‐ and Diastereoselectivity

Diene ligands significantly enhance the selectivity of Rh-catalyzed alkene hydrosilylation, resulting in highly regio- and diastereoselective production of 1,3-trans-oxasilacyclopentanes.

THE CHEMISTRY OF SOME NOVEL RHODIUM AND IRIDIUM COMPLEXES *

This paper presents a simple route to pentamethylcyclopentadienyl-rhodium and -iridium complexes, which enable detailed mechanistic studies of catalytic and stoichiometric reactions with unsaturated organic molecules.

Immunofluorescent localization of calcitonin in the ultimobranchial gland of Rana temporaria and Rana pipiens

Calcitonin-like immunoreactivity has been demonstrated in the ultimobranchial gland of Rana temporaria and Rana pipiens, suggesting potential cross-reactivity between the amphibian hormone and anti-porcine calcitonin antibodies.

Recent Advances in Homogeneous Hydrogenation of Carbon-Carbon Multiple Bonds

Homogeneous hydrogenation of carbon-carbon multiple bonds shows promise for greater reproducibility, better control of catalyst poisons, and more specific catalyst designs.