One electron transfer chain decomposition of trifluoroacetone diperoxide: The first 1,2,4,5-tetroxane with O-transfer capability

doi:10.1016/0040-4039(92)89044-D

Paper

One electron transfer chain decomposition of trifluoroacetone diperoxide: The first 1,2,4,5-tetroxane with O-transfer capability

Published Sep 22, 1992 · W. Adam*, G. Asensio, R. Curci

Tetrahedron Letters

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18

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Abstract

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Study Snapshot

Trifluoroacetone diperoxide is the first 1,2,4,5-tetroxane with O-transfer capability, capable of converting into trifluoroacetone and dioxygen through a reductive electron transfer chain reaction.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

One electron transfer chain decomposition of trifluoroacetone diperoxide: The first 1,2,4,5-tetroxane with O-transfer capability

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References

Mechanism of the thermal decomposition of substituted tetraoxanes in benzene solution: effect of substituents on the activation parameters of the unimolecular reactions

Substituted tetraoxanes in benzene solution undergo thermal decomposition, with activation parameters influenced by substituent effects in the tetraoxacyclohexane ring.

Solvent effects in the thermal decomposition reactions of cyclic ketone diperoxides

Acetone cyclic diperoxide (ACDP) reaction is more sensitive to solvent changes, resulting in different ground or transition states for its unimolecular reactions.

Citations

Chemiluminescence in the reaction of 1,2,4,5-tetraoxanes with ferrous ions in the presence of xanthene dyes: fundamentals and perspectives of analytical applications

Chemiluminescence (CL) is a promising method for the analytical detection of 1,2,4,5-tetraoxanes, with potential applications in biological research.

Tetraoxanes: Synthetic and Medicinal Chemistry Perspective

Tetraoxane-based antimalarials show significant promise due to their artemisinin-like activity, offering potential replacements for traditional drugs like chloroquine and mefloquine.

1,1,1‐Trifluoroacetone

1,1,1-trifluoroacetone is a valuable trifluoromethyl-containing building block for syntheses of various fluoroorganics, with various synthetic routes available for its preparation.

Chemiluminescence during interaction of 1,2,4-trioxolanes and 1,2,4,5-tetraoxanes with iron compounds

Chemiluminescence is observed in the reactions of 1,2,4-trioxolanes and 1,2,4,5-tetraoxanes with iron compounds, providing insights into their biological importance.

Synthesis and in vitro antimalarial activity of tetraoxane-amine/amide conjugates.

Tetraoxane-amine/amide conjugates show slightly better antimalarial activity than parent tetraoxanes, with potential activity at 0.38-0.80 M and no cytotoxicity observed in cancer and non-cancer cell lines.