Facile Insertion of Rh and Ir into a Boron-Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes.

doi:10.1021/jacs.5b11706

Paper

Facile Insertion of Rh and Ir into a Boron-Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes.

Published Feb 10, 2016 · Wei-Chun Shih, Weixing Gu, Morgan C. MacInnis

Journal of the American Chemical Society

Q1 SJR score

86

Citations

0

Influential Citations

Full textSemantic Scholar

Abstract

The unexpectedly facile insertion of Rh or Ir into a B-Ph bond (reversible for Rh) converts a borane/bis(phosphine) precursor into a boryl/bis(phosphine) PBP pincer ligand. Interconversions between the boryl/borane/borate central functionality are demonstrated in reactions with dihydrogen.

Highly Cited

Study Snapshot

Rh and Ir insertion into a boron-phenyl bond leads to boryl/bis(phosphine) PBP pincer complexes, with interconversions between boryl/borane/borate central functionality demonstrated in reactions with dihydrogen.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

Sign up to use Study Snapshot

Consensus is limited without an account. Create an account or sign in to get more searches and use the Study Snapshot.

Create an account

Facile Insertion of Rh and Ir into a Boron-Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes.

Sign up to use Study Snapshot

References

Citations