Paper
Facile synthesis of pyrroles via Rh(II)-catalyzed transannulation of 1-tosyl-1,2,3-triazoles with silyl or alkyl enol ethers
Published Nov 19, 2014 · Juan Feng, Yuanhao Wang, Qingong Li
Tetrahedron Letters
Q3 SJR score
28
Citations
0
Influential Citations
Abstract
Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.
Study Snapshot
Rh(II)-catalyzed transannulation of 1-tosyl-1,2,3-triazoles with silyl or alkyl enol ethers enables facile synthesis of substituted pyrroles in a regiocontrollable manner.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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References
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Rhodium(II)-catalyzed aza-[4+3] cycloadditions of 1-sulfonyl 1,2,3-triazoles with 1,3-dienes enable efficient synthesis of highly functionalized 2,5-dihydroazepines and 2,
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Citations
Synthesis of 2,3-Dihydropyrroles by Rhodium(II)-Catalyzed Transannulation of N-Sulfonyl-1,2,3-triazoles: Diversity Generation by One-Pot Methodologies.
This one-pot strategy allows for the synthesis of diverse compounds of synthetic interest, including 2,3-dihydropyrroles, in 13-76% yield using alkenes and rhodium catalysis.
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The developed method efficiently synthesizes highly substituted 3-azapyrroles using a one-pot process, with a wide range of substituents tolerated.
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Boron Trifluoride-Mediated Cycloaddition of 3-Bromotetrazine and Silyl Enol Ethers: Synthesis of 3-Bromo-pyridazines.
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