Paper
Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT
Published Oct 1, 2012 · L. Li, Genping Huang, Zhou Chen
European Journal of Organic Chemistry
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Abstract
The successful application of gallium trichloride as a catalyst for the intermolecular hydroamination of alkynes with aromatic amines is reported. The reaction is effective with many aniline derivatives and shows exclusive selectivity for the Markovnikov products. The mechanism of the transformation was investigated by DFT calculations and a plausible pathway is proposed.
Study Snapshot
Key takeawayGallium trichloride effectively catalyzes hydroamination of alkynes with aromatic amines, showing exclusive selectivity for Markovnikov products and a plausible pathway proposed by DFT calculations.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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