Homolytic aromatic ipso substitutions in benzothiazoles by the nucleophilic 1-adamantyl radical
Published Sep 6, 1977 · M. Fiorentino, L. Testaferri, M. Tiecco
Journal of The Chemical Society, Chemical Communications
UNKNOWN SJR score
14
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0
Influential Citations
Abstract
1-Adamantyl radicals react with several 2-substituted benzothiazoles to afford 2-(1-adamantyl)-benzothiazole as a result of a homolytic substitution occurring at the ipso position; the yields are greater when the groups to be displaced are electron-withdrawing.
Study Snapshot
Key takeawayThis reaction leads to the formation of 2-(1-adamantyl)-benzothiazole, with greater yields when the electron-withdrawing groups are present.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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