Homolytic aromatic ipso substitutions in benzothiazoles by the nucleophilic 1-adamantyl radical

doi:10.1039/C39770000316

Paper

Homolytic aromatic ipso substitutions in benzothiazoles by the nucleophilic 1-adamantyl radical

Published Sep 6, 1977 · M. Fiorentino, L. Testaferri, M. Tiecco

Journal of The Chemical Society, Chemical Communications

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14

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0

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Abstract

1-Adamantyl radicals react with several 2-substituted benzothiazoles to afford 2-(1-adamantyl)-benzothiazole as a result of a homolytic substitution occurring at the ipso position; the yields are greater when the groups to be displaced are electron-withdrawing.

Study Snapshot

This reaction leads to the formation of 2-(1-adamantyl)-benzothiazole, with greater yields when the electron-withdrawing groups are present.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Homolytic aromatic ipso substitutions in benzothiazoles by the nucleophilic 1-adamantyl radical

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