Paper
Insights into the mechanism of Nitrobenzene reduction to aniline over Pt catalyst and the significance of the adsorption of phenyl group on kinetics
Published Jun 1, 2016 · Tian Sheng, Y. Qi, Xiao Lin
Chemical Engineering Journal
Q1 SJR score
97
Citations
0
Influential Citations
Abstract
Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.
Highly CitedStudy Snapshot
The nitrobenzene reduction to aniline over a Pt catalyst occurs through a double H-induced dissociation of the N-O bond, with phenyl group adsorption significantly impacting kinetic barriers.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
Sign up to use Study Snapshot
Consensus is limited without an account. Create an account or sign in to get more searches and use the Study Snapshot.
Full text analysis coming soon...
References
Insights into the hydrogenation mechanism of nitrobenzene to aniline on Pd3/Pt(111): a density functional theory study
Nitrobenzene to aniline on Pd3/Pt(111) bimetallic surface preferentially follows the direct hydrogenation route, with phenylhydroxylamine being the rate-limiting step and almost exothermic processes.
2015·32citations·Lianyang Zhang et al.·RSC Advances
RSC Advances
Theoretical investigation of the decarboxylation and decarbonylation mechanism of propanoic acid over a Ru(0 0 0 1) model surface
To improve Ru catalyst performance for decarbonylation of organic acids, increasing free site coverage through catalyst promoters or increasing reaction temperature and low CO and H2 partial pressures is needed.
2015·49citations·Jianmin Lu et al.·Journal of Catalysis
Journal of Catalysis
Theoretical Investigation of the Reaction Mechanism of the Guaiacol Hydrogenation over a Pt(111) Catalyst
Pt(111) sites are not active deoxygenation sites, and the observed deoxygenation activity of Pt catalysts likely originates from the catalyst support or Pt step and corner sites.
2015·108citations·Jianmin Lu et al.·ACS Catalysis
ACS Catalysis
Coverage-Induced Conformational Effects on Activity and Selectivity: Hydrogenation and Decarbonylation of Furfural on Pd(111)
Increasing hydrogen coverage on Pd(111) alters the conformation of adsorbed furfural, affecting reaction rates and selectivity.
2015·152citations·Shengguang Wang et al.·ACS Catalysis
ACS Catalysis
Direct vs. indirect pathway for nitrobenzene reduction reaction on a Ni catalyst surface: a density functional study.
Direct reduction of nitrobenzene to aniline on a Ni catalyst surface is more favourable than indirect reduction, with parallel adsorption behavior being preferable over vertical adsorption behavior.
2014·87citations·A. Mahata et al.·Physical chemistry chemical physics : PCCP
Physical chemistry chemical physics : PCCP
Citations
High-throughput screening of a transition metal single-atom electrocatalyst for the CH3NO2 reduction reaction
Transition metal single-atom electrocatalysts on N-doped graphene exhibit excellent catalytic activity for the reduction of nitro compounds under mild conditions.
2024·1citation·Kefeng Xie et al.·International Journal of Hydrogen Energy
International Journal of Hydrogen Energy
In-Situ investigation of the catalytic hydrogenation reaction of 4-nitrothiophenol by using single Pt@Au nanowires as a new platform
Single Pt@Au nanowires are a promising platform for in-situ monitoring of catalytic hydrogenation reactions, with excellent catalytic activity, high stability, and good reproducibility.
2024·0citations·Qingshan Dai et al.·Journal of Alloys and Compounds
Journal of Alloys and Compounds
Catalytic Reduction of Aromatic Nitro Compounds to Phenylhydroxylamine and Its Derivatives
Catalytic reduction of aromatic nitro compounds to phenylhydroxylamine and its derivatives presents challenges and prospects, with potential applications in chemical intermediates and pharmaceuticals.
2024·0citations·Min Yu et al.·Molecules
Molecules
Selenium-doped porous-C3N4 decorated with Cu NPs, as an operative heterogenous catalyst for the nitroarenes reduction reaction
The Se-p-C3N4 /Cu nanocatalyst exhibits exceptional catalytic proficiency in hydrogenating nitroaromatic compounds, producing anilines in an environmentally friendly aqueous media.
2024·3citations·Nahid Sadat Nouri et al.·Journal of Molecular Structure
Journal of Molecular Structure
Crystal plane effect of copper with different oxides/hydroxides nano-composites on catalytic performance and mechanism towards the reduction of 4-nitrophenol
Copper oxide/hydroxide composites with CuO(111) and Cu(111) crystal planes show the best synergistic effect on the reduction of 4-nitrophenol, offering new ideas for designing novel catalysts.
2024·1citation·Mailidan Wumaer et al.·Molecular Catalysis
Molecular Catalysis
Insights into the Mechanism of Nitrobenzene Reduction to Aniline by Phosphomolybdic Acid Supported TM1 Single-Atom Catalysts.
The mechanism of nitrobenzene reduction to aniline by Pt1 supported on phosphomolybdic acid (-PMA) has been proposed, with a limiting potential of -0.19 V and polyoxometalate playing an electronic sponge role.
2024·1citation·C. Zhao et al.·Inorganic chemistry
Inorganic chemistry
Tuning the Fe–N4 electrocatalytic CH3NO2 reduction reaction based on axial ligands: A computational study
Axial ligands, such as CN, NC, and OH, can effectively enhance the activation of CH3NO2 through the Fe–N4 active site, improving the catalytic performance of the catalyst in amine reduction reactions.
2024·9citations·Shengyuan Xu et al.·Materials Today Sustainability
Materials Today Sustainability
Recent Progress Toward Electrocatalytic Conversion of Nitrobenzene.
Recent advancements in catalyst design for electrocatalytic nitrobenzene reduction reaction (eNBRR) focus on improving performance by regulating local microenvironment, electron and mass transport.
2023·3citations·Shaojun Zhu et al.·Small methods
Small methods