Paper
Iron catalyzed highly regioselective dimerization of terminal aryl alkynes.
Published May 31, 2011 · Ganesh Chandra Midya, Sushovan Paladhi, Kalyan Dhara
Chemical communications
63
Citations
1
Influential Citations
Abstract
Iron can catalyze head-to-head dimerization of terminal aryl alkynes to give the corresponding (E) selective conjugated enynes in high yields. A variety of substituted aryl acetylenes underwent smooth dimerization using catalytic FeCl(3) and DMEDA in the presence of KO(t)Bu.
Iron catalyzes highly regioselective dimerization of terminal aryl alkynes, yielding (E) selective conjugated enynes in high yields.
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