Paper
KHSO4-Catalyzed Synthesis of 1,1′-Oxybis(2-bromoethane-1,1-diyl)dibenzenes and 1-(1-(Benzyloxy)-2-bromoethyl)benzenes Under Solvent-Free Conditions
Published Jan 1, 2013 · G. Joshi, E. Suresh, S. Adimurthy
Synthetic Communications
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Abstract
Abstract An economical and green conversion of 2-bromo-1-phenylethanols and benzylic alcohols into 1,1′-oxybis(2-bromoethane-1,1-diyl)dibenzenes and 1-(1-(benyloxy)-2-bromomethy)benzenes catalyzed by KHSO4 under neat condition is described. The present protocol is facile and chemoselective without transition-metal catalyst/solvent, and the KHSO4 catalyst is recyclable. GRAPHICAL ABSTRACT
KHSO4-catalyzed green conversion of 2-bromo-1-phenylethanols and benzylic alcohols into 1,1′-oxybis(2-bromoethane-1,1-diyl)dibenzenes and 1-(1-(benzyl
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