The Selective Liquid-Phase Oxidation of 3,4,5-Trimethoxytoluene to 3,4,5-Trimethoxybenzaldehyde

doi:10.1246/BCSJ.61.1035

Paper

The Selective Liquid-Phase Oxidation of 3,4,5-Trimethoxytoluene to 3,4,5-Trimethoxybenzaldehyde

Published Mar 1, 1988 · N. Kitajima, Kazuya Takemura, Y. Moro-oka

Bulletin of the Chemical Society of Japan

Q2 SJR score

12

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0

Influential Citations

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Abstract

The selective liquid-phase oxidation of 3,4,5-trimethoxytoluene to 3,4,5-trimethoxybenzaldehyde, an important chemical intermediate for medicine production, was developed; when 2.0 mmol of the reactant was heated at 110°C for 2 h in an autoclave under 3 atm O2 with 10 ml of acetic acid in the presence of 0.75 mmol of Co(OAc)2–Mn(OAc)2 (3:1 mole ratio), a 92% yield of the aldehyde was obtained.

Study Snapshot

Selective liquid-phase oxidation of 3,4,5-trimethoxytoluene to 3,4,5-trimethoxybenzaldehyde yields a 92% yield, making it an important intermediate for medicine production.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

The Selective Liquid-Phase Oxidation of 3,4,5-Trimethoxytoluene to 3,4,5-Trimethoxybenzaldehyde

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References

The Liquid-Phase Oxidation of p-Methoxytoluene to p-Anisaldehyde with Co(OAc)2/Ce(OAc)3/Cr(OAc)3 Catalyst

The most effective catalyst for liquid-phase oxidation of p-methoxy toluene to p-anisaldehyde is Co(OAc)2–Ce(OAc)3–Cr(OAc)3, yielding 76% of p-anisaldeh

Citations

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