Novel hexakis (alkylthio) benzene with C3 symmetry: synthesis, crystal structure and physical properties of a tris-(ethylenedithio) benzene salt: (TEDTB)2BF4

doi:10.1016/0379-6779(86)90176-1

Paper

Novel hexakis (alkylthio) benzene with C3 symmetry: synthesis, crystal structure and physical properties of a tris-(ethylenedithio) benzene salt: (TEDTB)2BF4

Published Dec 1, 1986 · R. Lapouyade, J. Morand, D. Chasseau

Synthetic Metals

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12

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Abstract

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Study Snapshot

The synthesis of a new hexakis (alkylthio) benzene with C3 symmetry and its semiconducting behavior around room temperature suggest potential for exciting donor molecules.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

Novel hexakis (alkylthio) benzene with C3 symmetry: synthesis, crystal structure and physical properties of a tris-(ethylenedithio) benzene salt: (TEDTB)2BF4

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References

Structure and properties of cation-radical salts of arenes. II. Crystal structure, phase transitions and analysis of the electrochemical crystallization process of fluoranthenyl cation-radical salts

Fluoranthenyl radical cation salts, a new family of organic conductors, exhibit metal to semiconductor transitions due to distortion of aromatic stacks, and can function as electrodes when grown on anodes.

ESR of fluoranthenyl-radical-cation organic conductor crystals

Fluoranthenyl-radical-cation-salt crystals (FARK) show complex thermal behavior, with narrow ESR lines at g 2, and a complex thermal behavior at low, intermediate, and high temperatures.

Citations

Persulfurated aromatic compounds.

Persulfurated aromatic compounds offer unique properties and potential for designing redox sensors, ion-selective membranes, and nonlinear optical materials.

Sulfur Radical Cations

Sulfur radical cations show novel behavior, potential for organic synthesis, biological electron-transfer, and high electrical conductivity in materials based on sulfur compounds.

SYNTHESIS, PROPERTIES, AND STRUCTURES OF 1,2:5,6-BIS(ETHYLENEDITHIO)PYRACYLENE AND ITS RADICAL CATION SALTS

1,2:5,6-Bis(ethylenedithio)pyracylene synthesized shows potential as a reversible two-stage redox system with low oxidation potentials, enabling the synthesis of radical cation salts with hexafluorophosphate and trii

Radical Cation Salts of 2,3,8,9-Tetrahydro-1,4,7,10-tetrathiachrysene

The novel 2,3,8,9-tetrahydro-1,4,7,10-tetrathiachrysene (7) produces high electrical conductivity and good thermal stability when electrocrystallized into radical cation salts.

Ab initio study of 1,4-dithiin and its cation radical and dication

1,4-dithiin's structures show folded forms in neutral state and planar forms in cation and dication states, influenced by weak conjugation between sulfur and carbon atoms and sulfur atoms' interactions.

ESR, UV-visible and infrared spectroscopies of hexakis(alkylthio)benzene cations with C3 symmetry

Hexakis(alkylthio)benzene cations with C3 symmetry show more stability in acidic medium and higher second redox potential than HMT, but are less stable and have a singlet ground state in solid state.

Synthesis of Novel Hexakis (Alkylthio) Benzenes with C3 Symmetry. Physical Properties of Their Charge Transfer Complexes and Radical-Cation Salts

Novel hexakis (alkylthio) benzenes with C3 molecular symmetry have been synthesized and their magnetic properties have been characterized in potential ferromagnetic systems.