Organometallic derivatives. Part III. The displacement of hydroxy- and similar groups from α-substituted ferrocenylmethanes by aniline

doi:10.1039/J39710004000

Paper

Organometallic derivatives. Part III. The displacement of hydroxy- and similar groups from α-substituted ferrocenylmethanes by aniline

Published 1971 · G. Marr, B. W. Rockett, A. Rushworth

Journal of The Chemical Society C: Organic

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3

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0

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Abstract

Hydroxy-, dimethylamino-, phenoxy-, and piperidino-groups have been displaced by aniline from the corresponding α-substituted ferrocenylmethanes. The anilino-group has been displaced from anilinomethylferrocene by p-methoxyaniline. The nucleophilic character of the attacking group has been shown to be important in this displacement.

Study Snapshot

Aniline effectively displacements hydroxy-, dimethylamino-, phenoxy-, and piperidino-groups from -substituted ferrocenylmethanes, with the nucleophilic character of the attacking group being crucial.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Paper

Organometallic derivatives. Part III. The displacement of hydroxy- and similar groups from α-substituted ferrocenylmethanes by aniline

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References

Citations

One-pot α-ferrocenylalkylation of amines and alcohols with α-ferrocenyl substituted alcohols under acid-free conditions

This one-pot -ferrocenylalkylation method efficiently produces N-(-ferrocenylalkyl)amines and ethers with high yields, while also causing side reactions.