Paper
Palladium-catalysed regioselective addition reaction of ethyl phenylphosphinate with terminal acetylenes: ligand- and solvent-dependent regioselectivity.
Published Jul 4, 2007 · Satish Kumar Nune, Masato Tanaka
Chemical communications
Q1 SJR score
33
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0
Influential Citations
Abstract
Palladium-1,2-bis(diphenylphosphino)ethane complex catalyses regioselective Markovnikov addition of ethyl phenylphosphinate to terminal alkynes in toluene, while the use of tri-tert-butylphosphine as the ligand or ethanol as the solvent leads to regioselectivity reversal.
Study Snapshot
The palladium-catalyzed regioselective addition reaction of ethyl phenylphosphinate to terminal alkynes in toluene exhibits ligand- and solvent-dependent regioselectivity, with reversibility occurring when tri
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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