Paper
Selective oxidative para C-C dimerization of 2,6-dimethylphenol.
Published Nov 21, 2005 · C. Boldron, G. Aromí, G. Challa
Chemical communications
28
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Influential Citations
Abstract
Mechanistic investigations on the oxidative coupling of 2,6-dimethylphenol have led to the development of a selective and efficient procedure to prepare 3,5,3',5'-tetramethyl-biphenyl-4,4'-diol, via a C-C coupling, mediated by a hypervalent form of iodine, i.e. (diacetoxyiodo)benzene and for which a mechanism is proposed.
This study developed a selective and efficient procedure for preparing 3,5,3',5'-tetramethyl-biphenyl-4,4'-diol via oxidative coupling with (diacetoxyiodo)benzene, with a proposed mechanism.
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