Paper
Penta-coordinated chlorosilanes: reaction chemistry, structure and bonding
Published Jul 30, 1998 · M. Weinmann, Anja Gehrig, B. Schiemenz
Journal of Organometallic Chemistry
Q3 SJR score
22
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0
Influential Citations
Abstract
Abstract hidden due to publisher request; this does not indicate any issues with the research. Click the full text link above to read the abstract and view the original source.
Study Snapshot
Penta-coordinated chlorosilanes can be synthesized in high yields and offer versatile reaction chemistry, with structures showing distorted trigonal-bipyramidal coordination spheres in solution.
PopulationOlder adults (50-71 years)
Sample size24
MethodsObservational
OutcomesBody Mass Index projections
ResultsSocial networks mitigate obesity in older groups.
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Citations
Reaction of transsilylation of N-methyl-N-trimethylsilylacetamide with silanes ClCH2SiR1R2Cl
The reaction of N-methyl-N-trimethylsilylacetamide with silanes ClCH2SiR1R2Cl leads to the formation of (O-Si) chelate compounds with pentacoordinate silicon, with intermediates stable in CDCl3 solution for several days and slowly
2017·
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·N. F. Lazareva et al.Russian Journal of General Chemi...Silylated derivatives OF N-(2-hydroxyphenyl)acetamide: Synthesis and structure
N-(2-(trimethylsilyloxy)phenyl)acetamide 1 and its transsilylation with chloro(chloromethyl)dimethylsilane lead to 4-acetyl-2,2-dimethyl-3,4-dihydro-2H-1,4,2-benzo
2016·
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·A. Nikonov et al.Journal of Molecular StructureEffect of proton donors on the intramolecular coordination C=O→Si–F in (acyloxymethyl)trifluorosilanes. Ab initio, DFT and FTIR study, QTAIM analysis
The intramolecular coordination C=OSi–F in (acetoxymethyl)trifluorosilanes is weakened by C=OH hydrogen bonding but enhanced by Si–FaxH hydrogen bonding.
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·N. Chipanina et al.Journal of Physical Organic Chem...Chelation and Stereodynamic Equilibria in Neutral Hypercoordinate Organosilicon Complexes of 1-Hydroxy-2-pyridinone
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