Photoacid-catalyzed acetalization of carbonyls with alcohols.

doi:10.1039/d2ob00435f

Paper

Photoacid-catalyzed acetalization of carbonyls with alcohols.

Published Jul 25, 2022 · Jason Saway, Abigail F. Pierre, Joseph J. Badillo

Organic & biomolecular chemistry

Q2 SJR score

0

Citations

0

Influential Citations

Full textSemantic Scholar

Abstract

In this report, we demonstrate that visible light photoactivation of 6-bromo-2-naphthol facilitates the photoacid-catalyzed acetalization of carbonyls with alcohols. We also demonstrate that 2-naphthol when coupled to a photosensitizer provides acetals from electron-deficient aldehydes. In addition, the S1 excited state pKa for 6-bromo-2-naphthol in water was determined and shown to have increased excited-state acidity relative to 2-naphthol.

Study Snapshot

Visible light photoactivation of 6-bromo-2-naphthol facilitates photoacid-catalyzed acetalization of carbonyls with alcohols, providing acetals from electron-deficient aldehydes.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

Sign up to use Study Snapshot

Consensus is limited without an account. Create an account or sign in to get more searches and use the Study Snapshot.

Create an account

Photoacid-catalyzed acetalization of carbonyls with alcohols.

Sign up to use Study Snapshot

References

Citations