Photolysis of N-2,4-dinitrophenylamino-acids; Structural requirements for the formation of 6-nitrobenzimidazole 1-oxides.

doi:10.1039/J39690002127

Paper

Photolysis of N-2,4-dinitrophenylamino-acids; Structural requirements for the formation of 6-nitrobenzimidazole 1-oxides.

Published 1969 · D. Neadle, R. Pollitt

Journal of the Chemical Society. Perkin transactions 1

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4

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Abstract

6-Nitrobenzimidazole 1-oxides are formed from N-2,4-dinitrophenylamino-acids in optimum yields at very low pH and also at ca. pH 3. The reaction at pH 3 requires a hydrogen atom on the amino-group, whereas at low pH it does not. The mechanism of the reaction is discussed.

Study Snapshot

6-Nitrobenzimidazole 1-oxides are formed from N-2,4-dinitrophenylamino-acids at very low pH and also at ca. pH 3, with optimum yields at low pH and a hydrogen atom on the amino-group at ca. pH 3.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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Photolysis of N-2,4-dinitrophenylamino-acids; Structural requirements for the formation of 6-nitrobenzimidazole 1-oxides.

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