Paper
Polyoxomolybdate-Calix[4]arene Hybrid: A Catalyst for Sulfoxidation Reactions with Hydrogen Peroxide.
Published Oct 6, 2015 · Sara Meninno, A. Parrella, G. Brancatelli
Organic letters
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Abstract
An easily accessible polyoxomolybdate-calix[4]arene hybrid 1 has been synthesized and applied as a heterogeneous catalyst in the sulfoxidation of thioethers to sulfoxides and to sulfones under strictly stoichiometric amounts of 30% H2O2 in CH3CN as the solvent. This study represents the first promising example of successful employment of calixarenes-polyoxometalate (POM) hybrid materials in the area of catalytic oxidations.
The polyoxomolybdate-calix[4]arene hybrid 1 shows promise as a catalyst for sulfoxidation reactions with hydrogen peroxide, offering potential for industrial applications.
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