The properties of thiobenzyl esters of the P(III) acids. Part I. The study of the reaction mechanism of 2‐benzylthio‐4,5‐benzo‐1,3,2‐dioxaphospholane with ketones and oxygen by CIDNP 31P

doi:10.1002/HC.520030410

Paper

The properties of thiobenzyl esters of the P(III) acids. Part I. The study of the reaction mechanism of 2‐benzylthio‐4,5‐benzo‐1,3,2‐dioxaphospholane with ketones and oxygen by CIDNP 31P

Published Aug 1, 1992 · Y. Drozdova, A. Burilov, M. Pudovik

Heteroatom Chemistry

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Abstract

2-Benzylthio-4,5-benzo-1,3,2-dioxaphospholane reacts with oxygen to form the corresponding thiophosphonate, dithiophosphate and pyrophosphite. The reaction was found to be of a radical nature. The mechanism is suggested to involve an initial electron transfer with suitable subsequent transformations. The interaction of the title compound with various ketones in a pure oxygen atmosphere was studied by the CIDNP method.

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The reaction mechanism of 2-benzylthio-4,5-benzo-1,3,2-dioxaphospholane with ketones and oxygen involves initial electron transfer followed by suitable transformations.

PopulationOlder adults (50-71 years)

Sample size24

MethodsObservational

OutcomesBody Mass Index projections

ResultsSocial networks mitigate obesity in older groups.

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The properties of thiobenzyl esters of the P(III) acids. Part I. The study of the reaction mechanism of 2‐benzylthio‐4,5‐benzo‐1,3,2‐dioxaphospholane with ketones and oxygen by CIDNP 31P

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