Paper
The Reaction of 2-Ethoxy-1,3-dithiolane with Carbonyl Compounds
Published May 1, 1981 · Shigeo Jo, S. Tanimoto, T. Oida
Bulletin of the Chemical Society of Japan
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Abstract
The reaction of 2-ethoxy-1,3-dithiolane with carbonyl compounds such as aldehydes and ketones was investigated. The reaction proceeded smoothly in the presence of the HgCl2-catalyst to afford 2-substituted and 2,2-disubstituted 1,3-dithiolanes. The reaction also offers an interesting alternative to the previously reported methods of synthesizing 1,3-dithiolanes which involve the acid-catalyzed reaction of carbonyl compounds with 1,2-ethanedithiol.
The reaction of 2-ethoxy-1,3-dithiolane with carbonyl compounds produces 2-substituted and 2,2-disubstituted 1,3-dithiolanes, offering an alternative to acid-catalyzed reactions of carbonyl compounds with 1,2-ethanedit
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