Paper
Reaction of 5-substituted 4,6-dichloro-2-aminopyrimidines with oxalyl chloride
Published Sep 1, 1977 · I. Boldyrev, I. Vladimirtsev, E. A. Romanenko
Chemistry of Heterocyclic Compounds
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Abstract
The reaction of 5-substituted 4,6-dichloro-2-aminopyrimidines with oxalyl chloride gives 2-isocyanatopyrimidines, the structures of which were proved by chemical means and the IR, PMR, and 35Cl nuclear quadrupole resonance spectra. The intermediate pyrimidinyloxamic acid chlorides were not isolated; this is evidently explained by the low basicities of 2-amino-pyrimidines.
The reaction of 5-substituted 4,6-dichloro-2-aminopyrimidines with oxalyl chloride produces 2-isocyanatopyrimidines, with the intermediate pyrimidinyloxamic acid chlorides not isolated due to low basicities of 2-a
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